NMR evidence for the charge transfer from interstitial NO or O2 to molecule C60 in solid C60

Solid C₆₀ was stored in NO and O₂ under high pressure, and the molecule NO and O₂ were found to diffuse into the octahedral interstitial sites in its fcc crystal lattice. Their ¹³C NMR MAS spectra composed of a primary resonance at 143.7 ppm, accompanied by several minor peaks shifted downfield respectively. The spectra at various temperatures from 210 to 300 K have been measured, and the chemical shifts of the minor peaks referenced to the primary resonance versus inverse temperature show straight lines. But, the lines do not go through origin, and their intercepts are equal to 0.13 ppm or its multiple. Due to a non-zero intercept at high-temperature limit, we proposed that there is a charge transfer from NO and from O₂ to C₆₀. The quantity of the charge transferred has been calculated, that is about 0.065 q_e^- (q_e^- for the elementary charge on an electron).     

稀土元素原子发射光谱及其谱线干扰的高分辨率ICP—AES研究…

稀土元素在当今生产、生活中具有极重要的地位，由于稀土元素的原子发射光谱极为复杂，因此光谱干扰给稀土元素的原子发射光谱分析带来极大的困难。本工作利用高分辨率ＩＣＰ－ＡＥＳ仪器详细研究了Ｓｍ基体对其他稀土元素分析线的光谱干扰，获得了大量的光谱及光谱干扰信息，为以稀土为基体的痕量稀土分析线的选择及光谱分析提供了依据。     

Structures of energy spectrum and persistent currents in mesoscopic rings with radial potential barrier in magnetic field

The energy spectrum and the persistent currents are calculated for finite-width mesoscopic annular structures with radial potential barrier in the presence of a magnetic field. The introduction of the tunneling barrier leads to the creation of extra edge states around the barrier and the occurrence of oscillatory structures superimposed on the bulk Landau level plateaus in the energy spectrum. We found that the Fermi energy E _F increases with the number of electrons N emerging many kinks. The single eigenstate persistent current exhibits complicated structures with vortex-like texture, “bifurcation”, and multiple “furcation” patterns as N is increased. The total currents versus N display wild fluctuations.     

Coordination behavior of N-benzoylamino acids: Synthesis and structure of mixed-ligand complexes of palladium (II) with N-benzoylamino acid dianion and diamine

Four new mixed-ligand complexes of palladium (II) with L₁ (N-benwyl-α-amino acid dianion) and L₂ [ethyldiamine (en), 2. 2′-bipyridine (Bpy) and 1.10-phenanthroline (Phen)] were synthesized. All the complexes have been characterized by elemental analyses, molar conductance, infrared and¹H NMR spectra and thermo-gravimetric analyses. Crystal structures of [Pd(Bpy)(Bzval-N, O)] and [Pd(en)(Bzphe-N, O) ·H₂O have been determined by X-ray diffraction analysis. The results indicate that in all the complexes’ ligand L₁ coordinates to palladium (II) through deprotonated amide nitrogen and carboxylic oxygen, and there are some intramolecular noncovalent interactions in the complexes. Project supported by the Natural Science Foundation of Zhejiang Province, China.     

Polarisation characteristics of a 12 fibre coupler under femtosecond pulsed and continuous wave illumination

We report on the experimental investigation carried out in the polarisation characteristics of femtosecond pulsed and continuous wave beams propagating through a 1×2 fibre coupler. It is demonstrated that the polarisation states of pulsed and continuous wave illumination over the broad wavelength range can be preserved in a conventional fused fibre coupler. Furthermore, the fibre coupler acts as a low-pass spectral filter in the visible wavelength range with a splitting ratio between 99.6/0.4 and 99.7/0.3. The result is of importance for fibre-optic second harmonic generation microscopy which requires the polarisation preservation to extract molecular organization of a sample.     

Direct decoration of disclinations by solidification-induced band texture for a nematic side chain liquid crystalline polymer

For a nematic polymethacrylate side chain liquid crystalline polymer, g 154 N 298 I (°C), the solidification-induced band texture has been observed aligned along the disclination under a polarizing optical microscope, when the specimen was quenched from 280°C to room temperature. The decoration technique of solidification-induced band texture, which is usually reported for main chain liquid crystalline polymers, was then introduced to reveal the director field pattern along a disclination for this side chain liquid crystalline polymer. It was found by infra-red dichroism measurements that the director orientation is parallel with the direction of the band. On this basis, disclinations with strength s=±1/2 and s=±1 were mapped according to the corresponding pattern of solidification-induced band texture. In addition, two types of inversion wall, loop-like and splay-type walls, were also found to be decorated by the solidification-induced band texture.     

氯苯的同步辐射光电离研究

利用真空紫外同步辐射和反射式飞行时间质谱仪对氯苯进行了光电离研究,通过测量各离子的光电离效率(PIE)曲线,得到了氯苯的电离势为(9.11±0.05)eV及两种主要碎片离子C6H+5和C4H+3的出现势分别为(12.96±0.05)和(16.27±0.05)eV.结合有关文献的热力学数据,推导出C6H5Cl+、C6H+5及C4H+3的离子生成焓及一些键的解离能.实验获得了118.0nm同步辐射光电离下氯苯的质谱图.     

Mössbauer study of Fe-B alloys containing Nd additives

The influence of a few percent neodynium additives to Fe-B alloy on the hyperfine parameters was investigated. It was found that Nd decreases the hyperfine field of amorphous Fe-B alloys. The samples annealed at temperatures between 600°C and 700°C contain α-Fe and Fe₃B phases. The average hyperfine field of Fe₃B phase increases with increasing Nd content and decreases with increasing annealing temperature. The average isomer shift of Fe₃B phase decreases with increasing Nd content. The experimental data show that the change of hyperfine parameters of the Fe₃B phase in the studied alloys is due to Nd atom.     

一种求解虚波长路径光网络波长资源优化问题的启发式算法

本文提出了一种虚波长路径光网络的启发式路由选择算法,它可以用来解决以最小化网络所需波长数目为目标的资源优化问题.该算法应用了基于最大概率路径的选路优化策略.对一个样例网络的数值分析结果表明该算法是有效的.     

缺项幂级数的最小模与最大项(英文)

在本文中我们研究缺项幂级数的最小模与最大项间的关系，改进了Ｐ．Ｅｒｄｏｓ和Ａ．Ｊ．Ｍａｃｉｎｔｙｒｅ的结果